Online resource for learning Italian
MyLanguages.org Italian has a set of resources available for total beginner learners of Italian.
Covers Italian basics
These resources include information about the Italian alphabet, adjectives, adverbs, articles, gender, nouns, numbers, phrases, singular and plural, pronouns, verbs, vocabulary, translation, dictionary, video, audio, reading and transliteration.
Also included is a simple Italian phrasebook.
Free to start learning Italian
This resource allows you to get started with Italian and includes audio recordings of the vocabulary terms.
It's totally free:)